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聚六亚甲基胍盐酸盐在日化洗涤配伍性研究总结
2015-09-23

聚六亚甲基胍是一种国际新型安全无毒高分子聚合物抗微生物剂,国际通用名称为PHMG,具有杀菌效果好,毒性低,性能稳定,对皮肤和粘膜都无刺激,被应用于人体皮肤与粘膜、各类物体与表面、果蔬与养殖的消毒杀菌。

近来,发现其通过复配,也能与阴离子体系的洗手液、洗衣液、等沐浴露共存,并发挥很好作用。

总结如下:

1、PHMG与单一AES等阴离子表活不相容,形成胶体(有粘性,不溶于水,溶于酒精)后会大大降低抑菌性能;

2、PHMG与AEO-9,6501等非离子相容,复配时抑菌效果不变,甚至略有上升

3、PHMG与BS-12两性表活表活相容,在低浓度下,BS-12不影响PHMG的抑菌性能

4、PHMG与一定量的单一阴离子表活AESLASAEO-9吐温等非离子表活复配可变成澄清溶液,且不影响原有的抑菌性能;即阴离子表活形成的胶体物质可用AEO-9、吐温等来溶解。同时,在合适的范围中,能提高去污力、粘度、增容、面织类的柔顺等性能。

5、PHMG与一定量的单一阴离子表活AESLASAEO-9吐温等非离子表活复配可变成澄清溶液,与浓度,温度有关,与长链阴离子相对较易复配。

英超下注网址BIAO1  PHMG+AEO-9

PHMG,%

AEO-9,%

外观

抑菌环直径,mm

0

0.5

CHENGQINGRONGYE

(6)

0

1

CHENGQINGRONGYE

(7.5)

0

2

CHENGQINGRONGYE

(8.5)

0

4

CHENGQINGRONGYE

9

1.25

0

CHENGQINGRONGYE,BIAOYANG

8.5

12.5

0

CHENGQINGRONGYE,BIAOYANG

15.5

1.25

1

CHENGQINGRONGYE

9

1.25

2

CHENGQINGRONGYE

9.5

1.25

4

CHENGQINGRONGYE

10

 

 

英超下注网址BIAO2  PHMG+6501

PHMG,%

6501,%

外观

抑菌环直径,mm

0

0.5

RUBAIYETI

(7)

0

1

RUBAIYETI

(9.5)

0

2

RUBAIYETI

(11)

0

10

RUZHUANGNINGJIAO,JIBENTOUMING

12

1.25

0.5

FENCENG,BAISEXUZHUANGXUANFUWU

9.5

1.25

1

FENCENG,BAISEXUZHUANGXUANFUWU

10

1.25

2

FENCENG,BAISEXUZHUANGXUANFUWU

10.5

 

 

BIAO3PHMG+6501+AEO-9

序号

PHMG,%

6501,%

AEO-9,%

外观

抑菌环直径,mm

1

12.5

0.5

1

CHENGQINGRONGYE

15.5

2

12.5

1

2

CHENGQINGRONGYE

15

 

BIAO4PHMG+BS-12

PHMG,%

BS-12,%

外观

抑菌环直径,mm

0

1

CHENGQINGRONGYE

(6)

0

2

CHENGQINGRONGYE

(6)

0

4

CHENGQINGRONGYE

(6)

1.25

1

CHENGQINGRONGYE

8.5

1.25

2

CHENGQINGRONGYE

8.5

1.25

4

CHENGQINGRONGYE

8.5

 

 

英超下注网址BIAO5  PHMG+AES

PHMG,%

AES,%

外观

抑菌环直径,mm

0

1

CHENGQINGRONGYE

(7)

0

2

CHENGQINGRONGYE

(8)

0

3

CHENGQINGRONGYE

(9)

0

10

CHENGQINGRONGYE

11

2.5

1

FENCENG,BANTOUMINGXUANFUWU

8

2.5

2

FENCENG,BANTOUMINGXUANFUWU

(6.5)

2.5

3

FENCENG,BANTOUMINGXUANFUWU

(6)

 

英超下注网址BIAO6  PHMG+AES+AEO-9

序号

PHMG,%

AES,%

AEO-9,%

外观

抑菌环直径,mm

1

0

1

0.5

CHENGQINGRONGYE

(6)

2

0

1

1

CHENGQINGRONGYE

(6)

3

2.5

1

0.5

RUYE,DIBUSHAOLIANGYOUZHUANGWU

8

4

2.5

4

1

CHENGQINGRONGYE

8.5-9

 

 

BIAO7  PHMG+AOS

序号

PHMG,%

AOS,%

外观

抑菌环直径,mm

1

0

1

CHENGQINGRONGYE

(7)

2

0

2

CHENGQINGRONGYE

(6)

3

0

3

CHENGQINGRONGYE

9

4

0

10

CHENGQINGRONGYE

11

5

2.5

1

FENCENG,BANTOUMINGXUANFUWU

8

6

2.5

2

FENCENG,BANTOUMINGXUANFUWU

8

7

2.5

3

FENCENG,BANTOUMINGXUANFUWU

7

 

英超下注网址BIAO10PHMG+A445N

序号

PHMG,%

A445N,%

外观

抑菌环直径,mm

1

0

1

CHENGQINGRONGYE

(6)

2

0

2

CHENGQINGRONGYE

(6)

3

0

3

CHENGQINGRONGYE

(6)

4

2.5

1

BIMIANXIFUYOUZHUANGTOUMINGYETI

(6.5)

5

2.5

2

BIMIANXIFUYOUZHUANGTOUMINGYETI

(6)

 

BIAO8  PHMG+HUANGSUANNA

序号

PHMG,%

磺酸钠,%

外观

抑菌环直径,mm

1

0

1

CHENGQINGRONGYE

15

2

0

2

CHENGQINGRONGYE

21

3

0

3

CHENGQINGRONGYE

22

4

0

10

CHENGQINGRONGYE

27

5

2.5

1

RUYE,BAISEXUANFUGUTI

8

6

2.5

2

RUYE,BAISEXUANFUGUTI

(6)

7

2.5

3

RUYE,BAISEXUANFUGUTI

9

 

 

BIAO9  PHMG+HUANGSUANNA+AEO-9

PHMG,%

磺酸钠,%

AEO-9,%

外观

抑菌环直径,mm

0

1

1

CHENGQINGRONGYE

9

0

1

2

CHENGQINGRONGYE

(7)

2.5

1

1

RUYE,DIBUBAISEGUTICHENDIAN

8.5

1.5

1

4

CHENGQINGYETI

9

12.5

1

2

CHENGQINGYETI

16

 

 

英超下注网址BIAO11 PHMG+JIAZAO

序号

PHMG,%

钾皂,%

外观

抑菌环直径,mm

1

0

1

CHENGQINGRONGYE

(6)

2

0

2

CHENGQINGRONGYE

(6)

3

0

3

CHENGQINGRONGYE

(6)

4

0

10

CHENGQINGRONGYE

(9)

5

2.5

1

FENCENG,BANTOUMINGXUANFUWU

8

6

2.5

2

FENCENG,BANTOUMINGXUANFUWU

7

7

2.5

3

FENCENG,BANTOUMINGXUANFUWU

6.5

 

BIAO12PHMG+JIAZAO+AEO-9

序号

PHMG,%

钾皂,%

AEO-9,%

外观

抑菌环直径,mm

1

12.5

1

1

CHENGQINGRONGYE

15-15.5

2

12.5

1

2

CHENGQINGRONGYE

15.5-16

 

 

英超下注网址BIAO13  PHMG+HUNHEBIAOMIANHUOXINGJI

PHMG

,%

AEO-9

%

钾皂

%

BS-12

%

AOS

,%

AES

,%

6501

%

磺酸钠,%

A445N

%

柠檬酸钠,%

外观

抑菌环直径

,mm

1.0

2.5

1

0.5

1

2

0.5

0.5

0

0

CHENGQINGRONGYE

8.5

0

2

1

0.5

1

1

0.5

0

0

0

CHENGQINGRONGYE

(6.5)

2.5

2

1

0.5

1

1

0.5

0

0

0

CHENGQINGRONGYE

8.5-9

0

2

1

0.5

1

1

0.5

0

0

1

CHENGQINGRONGYE

(6.5)

2.5

2

1

0.5

1

1

0.5

0

0

1

CHENGQINGRONGYE

8-8.5

2.5

2

1

0.5

1

1

0.5

0

2

1

CHENGQINGRONGYE

(6.5)

 

 

 

 

 

 

 

 

 

 

 

 

 

               BIAO14 YUSHIMIANXIYIYEPEIWUQINGKUANG

PHMG,1%

LANYUELIANGSHENCHENJIEJINGHULIXIYIYE

CHENGQINGRONGYE

PHMG,1%

LIBAIQUANXIAOHULIXIYIYE

CHENGQINGRONGYE

PHMG,1%

AOMIAOXIYIYE

HUNZHUO

PHMG,1%

MIAOGUANJIACHAOXIAOXIYIYE

CHENGQINGRONGYE

PHMG,1%

CHAONENGSHUANGLIZIXIYIYE

HUNZHUO

PHMG,1%

MIAOJIEXINXIYIYE

HUNZHUO

ZHU:1、SUOYOUDEBIAOMIANHUOXINGJIDEYONGLIANGDOUYISHISHOUCHANPINWEIJICHU

2、所述PHMG25%市售产品浓度为基础

 

                   

 

WANGSHANGKEPU:

SHENMESHIJULIUYAJIAJIGUA?

英超下注网址JULIUYAJIAJIGUASHIYIZHONGGUOJIXINXINGANQUANWUDUGAOFENZIJUHEWUKANGWEISHENGWUJI,GUOJITONGYONGMINGCHENGWEIPHMG,HUAXUEXINGZHIWEIYANGLIZIJUHEWU,YOUDUOZHONGYANSHENGWU,LIRU:YANSUANYAN,BINGSUANYANHELINSUANYANDENG,BUTONGYANSHENGWUCHANPIN,QIXINGZHUANGGONGNENGYOUSUOBUTONG。

英超下注网址JULIUYAJIAJIGUADUIGELANSHIYINXINGJUN、GELANSHIYANGXINGJUN、BINGDU、ZHENJUNDENGDUOZHONGWEISHENGWUYOUSHAMIEHEYIZHIZUOYONG,SHIMUQIANSUOZHISHAJUNPUZUIGUANGDEJUHEWUKANGWEISHENGWUJI。

英超下注网址JULIUYAJIAJIGUAZAIZHONGGUODETUIGUANGLICHENG

90NIANDAI      XINYIDAIGUALEIGAOFENZIKANGWEISHENGWUJIJULIUYAJIAJIGUA(YINGWENJIANCHENGPHMG)ZAIOUZHOUWENSHI。

2000.9      OUZHOUZISHENGAOFENZIHUAXUEZHUANJIAJIANGJULIUYAJIAJIGUATUIGUANGDAOZHONGGUOSHANGHAIGUANGZHOUDENGDIQU。

2000.10     ZHONGGUOGUANGDONGZHONGSHANYIKEDAXUEGONGGONGWEISHENGXUEYUANWANCHENGDUI(PHMG)ANQUANXINGJIANCE。QIZHONGDUXINGJIANCE:2%PHMGXIAOSHUJINGKOUJIXINGDUXINGSHIYANJIEGUOWEILD50>20900mg/kg。PIFUCIJIXINGJIANCE:2%PHMGDUIXINXILANDABAITUDEPIFUCIJIJIFENZHIWEI0,SHUWUCIJIXING。

英超下注网址2000.10     ZHONGGUOGUANGZHOUGONGYEWEISHENGWUJIANCEZHONGXINWANCHENGDUIPHMGYUJIANYANDUICHANGJIANZHIBINGJUNDEKANGJUNXIAOGUODUIBIJIANCE,JIEGUOXIANSHI:PHMGDEDUIGELEIZHIBINGJUNDEKANGYIJUNXIAOGUOYOUYUJIANYANLEIXIAODUYE,PHMGKANGJUNXIAOLVGAOCHU10~15BEI。

2001.7      ZHONGGUOSHANGHAIDIERJUNYIDAXUELIUXINGBINGXUEJIAOYANSHIWANCHENGDUIPHMGDUIWAIKEPIFUCHANGJIANZHIBINGJUNJINHUANGSEPUTAOQIUJUNDEZUIDIYIJUNNONGDU(MIC)JIANCE,SHIYANZHENGMING:PHMGDUIJINHUANGSEPUTAOQIUJUNMINGAN,XIAOGUOXIANZHU。

英超下注网址2001        ZHONGGUOSHANGHAI、SHANDONGDENGDIQUQIYESHIYONGPHMGXISHIYESHENGCHANDEHUANBAOGAOXIAOXIAODUCHANPIN,QUDEGUOJIAWEISHENGBUXIAODUCHANPINPIZHUNWENHAO:LIRU,WEIYIPAIXIAODUYE、MATOUPAIBOSITEXIAODUYEDENG。GUOJIXIANJINJISHUZHENGSHIJINRUZHONGGUO。

2002.7      ZHONGGUOGUOJIAWEISHENGBUWEISHENGXITONGJIXIAODUQIYEGUIFANXINGBIAOZHUN,JIWEISHENGBU2002BAN《XIAODUJISHUGUIFAN》JIANGJULIUYAJIAJIGUA(PHMG)LIERUCHANGYONGXIAODUYEBEIXUANXIANGMU。

JULIUYAJIAJIGUADETEDIANHEYOUDIAN

SHAJUNPUGUANG,ZUOYONGSUDUKUAI,CHIJIUYIJUN,DUIRENTIJIDONGWUANQUANSHUSHI,DUIPIFUJIYANJINGWUCIJIXING,XINGNENGWENDING,YIYUPEIWU,NAIGAOWEN,WUFUSHIXING,WUMINGXIANQIWEIJIYANSE,BUPIAOBAI、BUZHESE,BUHANQIAN、GONG、XINDENGZHONGJINSHU,DUIHUANJINGYOUHAO。

英超下注网址JULIUYAJIAJIGUADEJIANDINGFANGFA

JULIUYAJIAJIGUAZUOWEIHUANBAO、ANQUANDEGAOFENZIJUHEWUKANGWEISHENGWUJI,ZI2000NIANJINRUZHONGGUOYILAI,YIBEIDUOGEXINGYERENKEHESHIYONG。DANSHI,JINNIANLAIZAISHICHANGSHANGYEYOUJIAMAODE、BUHEGEDEJULIUYAJIGUACHUXIAN,JIBUFENQIYEYONGHUDAILAILEKUNRAO,YIXIATIGONGJIZHONGKEXINGDEJIANBIEJULIUYAJIAJIGUADEFANGFA:

聚合度识别法

JULIUYAJIAJIGUAWEIYANGLIZIGAOFENZIJUHEWU。RUGUOSUOJIANCEDEWUZHIMEIYOUJUHEDU,NEIGAIWUZHIYIDINGBUSHIJULIUYAJIAJIGUA。LINGWAI,RUGUOYOUJUHEDU,DANSHIJUHEDUGUOGAOHUOGUODIYEBUZHENGCHANG,BIXUZAIYIDINGDEQUJIANZHINEI,FOUZEJIUYOUKENENGSHIBUHEGEDEJULIUYAJIAJIGUA,KECAIYONGXIANGGUANFANGFAJIANCE。

味觉识别法

JULIUYAJIAJIGUAZAIGAONONGDUXIAYONGSHETOUQIANCHANG,YOUYIZHONGTESHUDEWEIDAO(JULIUYAJIAJIGUAJISHIZAIGAONONGDUXIADUIRENTIYEMEIYOUHENMINGXIANDEDUXING,QIANCHANGHOUJIANYIJISHISHUKOUQINGXI),JIANYIZAIZHUANYEZHIDAOXIACAOZUO。

活性物质含量识别法

英超下注网址CAIYONGKEJIANGUANGFENGUANGGUANGDUYIFENXIFANGFAJIANCE。ANZHAOBIAOZHUNJIANCE,JIAN《YIYUANXIAODUJISHUGUIFAN》。

微生物检测法

0.2%DEJULIUYAJIAJIGUAXISHIYEYINGDANGZAI2FENZHONGNEI,DUIDAIBIAOJUNZHONGJINHUANGSEPUTAOQIUJUNDESHAMIELVDAYU99%,DUIDACHANGGANJUNDESHAMIELVDAYU99%,DUIBAISENIANZHUJUNDESHAMIELVDAYU99%,BINGQIE,DUIDAIBIAOJUNZHONGHEIQUMEIJUNDEYIJUNXIAOGUOXIANZHU。

HUOXINGWUZHIHANLIANGBIAOZHUNJIANCEFANGFA

JIAN《YIYUANXIAODUJISHUGUIFAN》JULIUYAJIAJIGUABUFEN。

英超下注网址HUOXINGWUZHIHANLIANGKUAISUJIANCEFANGFA

英超下注网址YOUYUPHMGDEBIAOZHUNJIANCEFANGFAJISHUYAOQIUJIAOGAO,SHIJICAOZUOSHIKENENGCUNZAIYIDINGDENANDU,WEICI,GAOJUCHUANGJIANLEYITAOJIANYIDEKUAISUJIANCEFANGFA,SHIJIANZHENGMING,KEBANGZHUYONGHUGENGHAODIGUANKONGCHANPINZHILIANG。

JULIUYAJIAJIGUADEYINGYONGLINGYU

JULIUYAJIAJIGUADUIGELANSHIYINXINGJUN、GELANSHIYANGXINGJUN、BINGDU、ZHENJUN、LIUSUANYANHAIYUANJUN、TIEXIJUNDENGJIHUSUOYOUXIJUNYOUSHAMIEHEYIZHIZUOYONG,BINGQIEYOUYUCHANPINWEIJUHEWUXINGZHI,XINGNENGWENDING、YIYUPEIWU,DUIRENTIJIDONGWUANQUANXINGGAO,SHUSHIXINGHAO,KEGUANGFANYINGYONGYUYILIAOWEISHENG、SHUICHULI、SHIJIN、YANGZHI、CHUMU、SHUICHAN、ZHONGZHI、FANGZHI、WEISHENGYONGPIN、SHENGHUOYONGZHI、SULIAO、TULIAO、RIYONGHUAXUEPINDENGDUOZHONGLINGYU

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